2D CC-CTUC Solids

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Line 20: Line 20:
time: rlx @a t1 @b t2 @c t3 @d t4 @e t5 @f t5 @g t6 @h d @i
time: rlx @a t1 @b t2 @c t3 @d t4 @e t5 @f t5 @g t6 @h d @i
-
rf H: 90@a wp@a1,b=irr wp@b1--------------------------------------g=fulldec wp@h1----i=acqdec
+
rf H: 90@a=phy wp@a1,b=posramp wp@b1--------------------------------------g=fulldec wp@h1----i=acqdec
-
rf 13C: wp@a2,b=posramp 180@c 90@d 90@e 180@f 90@g 90@h acq@h1----i
+
rf 13C: wp@a2,b=irr 180@c=phx 90@d=phy 90@e=phx 180@f=phy 90@g=phx 90@h=phmx acq@h1----i
rf 15N: wp@h1----i
rf 15N: wp@h1----i
Line 30: Line 30:
delay t5: show_at=13C label=\tau
delay t5: show_at=13C label=\tau
delay t6: show_at=13C label=\tau_{zf}
delay t6: show_at=13C label=\tau_{zf}
 +
 +
pulse p1: phase=phi1
 +
 +
pulse phx: phase=px
 +
pulse phmx: phase=mx
 +
pulse phy: phase=py
 +
 +
phase px: label=x
 +
phase py: label=y
 +
phase mx: label=-x
delay rlx: hide=true
delay rlx: hide=true
Line 39: Line 49:
pulse p1: phase=phi1
pulse p1: phase=phi1
-
wp irr: h1=65
+
wp irr: h1=65 label=x
-
wp posramp: h1=65 h2=95
+
wp posramp: h1=65 h2=95 label=x
wp fulldec: h1=100 label=SPINAL
wp fulldec: h1=100 label=SPINAL
wp acqdec: h1=75 label=SPINAL
wp acqdec: h1=75 label=SPINAL
Line 85: Line 95:
phase phi2: label=\phi_2 table=1,3
phase phi2: label=\phi_2 table=1,3
</pulse>
</pulse>
 +
 +
===CACO IPAP (IP) Version===
 +
<pulse>
 +
anchors: @a,a1,a2 @b,b1 @c @c1,d,d1 @e @f @g @h------h1 @i
 +
disp: 4@a 5@b 7@c 7@d 1@e 7@f 7@g 4@h 10@i
 +
time: rlx @a t1 @b t2 @c t3 @d t4 @e t5 @f t5 @g t6 @h d @i
 +
 +
rf H: 90@a wp@a1,b=irr wp@b1--------------------------------------g=fulldec wp@h1----i=acqdec
 +
rf 13C: wp@a2,b=posramp 180@c 90@d 90@e 180@f 90@g 90@h acq@h1----i
 +
rf 15N: wp@h1----i
 +
 +
delay t1: show_at=13C label=ct label_yoffset=-30
 +
delay t2: show_at=13C label=\tau_1-\frac{t_1}{2}
 +
delay t3: show_at=13C label=\tau_1+\frac{t_1}{2}
 +
delay t4: hide=true
 +
delay t5: show_at=13C label=\tau_2
 +
delay t6: show_at=13C label=\tau_{zf}
 +
 +
delay rlx: hide=true
 +
delay d: hide=true
 +
 +
rfchan 13C: label=^{13}C
 +
rfchan 15N: label=^{15}N
 +
rfchan H: label=^1H
 +
 +
pulse p1: phase=phi1
 +
wp irr: h1=65
 +
wp posramp: h1=65 h2=95
 +
wp fulldec: h1=100 label=SPINAL
 +
wp acqdec: h1=75 label=SPINAL
 +
acq: phase=phi2 type=fid
 +
 +
phase phi1: table=0,2 label=\phi_1
 +
phase phi2: label=\phi_2 table=1,3
 +
</pulse>
 +
 +
===CACO IPAP (AP) Version===
 +
<pulse>
 +
anchors: @a,a1,a2 @b,b1 @c @c1,d,d1 @e @f @g @h------h1 @i
 +
disp: 4@a 5@b 7@c 7@d 1@e 7@f 7@g 4@h 10@i
 +
time: rlx @a t1 @b t2 @c t3 @d t4 @e t5 @f t5 @g t6 @h d @i
 +
 +
rf H: 90@a wp@a1,b=irr wp@b1--------------------------------------g=fulldec wp@h1----i=acqdec
 +
rf 13C: wp@a2,b=posramp 180@c 90@d 90@e shp@f=COsoft acq@h1----i
 +
rf 15N: wp@h1----i
 +
 +
delay t1: show_at=13C label=ct label_yoffset=-30
 +
delay t2: show_at=13C label=\tau_1-\frac{t_1}{2}
 +
delay t3: show_at=13C label=\tau_1+\frac{t_1}{2}
 +
delay t4: hide=true
 +
delay t5: show_at=13C label=\tau_2
 +
delay t6: show_at=13C label=\tau_{zf}
 +
 +
delay rlx: hide=true
 +
delay d: hide=true
 +
 +
rfchan 13C: label=^{13}C
 +
rfchan 15N: label=^{15}N
 +
rfchan H: label=^1H
 +
 +
pulse p1: phase=phi1
 +
wp irr: h1=65
 +
wp posramp: h1=65 h2=95
 +
wp fulldec: h1=100 label=SPINAL
 +
wp acqdec: h1=75 label=SPINAL
 +
acq: phase=phi2 type=fid
 +
 +
phase phi1: table=0,2 label=\phi_1
 +
phase phi2: label=\phi_2 table=1,3
 +
</pulse>
 +
==References==
==References==

Revision as of 21:45, 4 September 2008

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Name: hCC-2D-CTUC COSY
Experiment family/families: solids
Synopsis: Constant-time Through-bond Carbon 2D correlation experiments
Implementation author(s): L. Chen, D.W. Elliot, J.M. Boetcher, D.H. Zhou, C.M. Rienstra, L.J. Mueller
Copyright: not assigned
Console: Varian, Infinity Plus, 500 MHz
Download: code, no sample/parameter data yet

CO-CA Version

Pulse sequence image

Aliphatic Version

Pulse sequence image

CACO IPAP (IP) Version

Pulse sequence image

CACO IPAP (AP) Version

Pulse sequence image


References

  1. Chen, L and Olson, RA and Elliot, DW and Boettcher, JM and Zhou, DH and Rienstra, CM and Mueller, LJ. Constant-Time Through-Bond ^{13}C Correlation Spectroscopy for Assigning Protein Resonances with Solid-State NMR Spectroscopy. J Am Chem Soc 128(31):9992--9993, 2006. BibTeX [bbCTUC]
  2. Chen, L and Kaiser, JM and Lai, J and Polenova, T and Yang, J and Rienstra, CM and Mueller, LJ. J-based 2D homonuclear and heteronuclear correlation in solid-state proteins. Magn Reson Chem 45 suppl.:s84-s92, 2007. BibTeX [ipapCTUC]

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