2D CC-CTUC Solids

From NMR Wiki

(Difference between revisions)
Jump to: navigation, search
(CO-CA Version)
Line 1: Line 1:
{{pulse-sequence
{{pulse-sequence
-
|name=hCC-2D-DARR
+
|name=hCC-2D-CTUC COSY
-
|synopsis=Simple Carbon or Nitrogen 2D experiment with DARR (RAD) broadband mixing
+
|synopsis=Constant-time Through-bond Carbon 2D correlation experiments
|author=L. Chen, D.W. Elliot, J.M. Boetcher, D.H. Zhou, C.M. Rienstra, L.J. Mueller
|author=L. Chen, D.W. Elliot, J.M. Boetcher, D.H. Zhou, C.M. Rienstra, L.J. Mueller
|code=I+CTUC_COSY.txt
|code=I+CTUC_COSY.txt
Line 20: Line 20:
time: rlx @a t1 @b t2 @c t3 @d t4 @e t5 @f t5 @g t6 @h d @i
time: rlx @a t1 @b t2 @c t3 @d t4 @e t5 @f t5 @g t6 @h d @i
-
rf H: 90@a wp@a1,b=irr wp@b1--------------------------------------g wp@h1----i
+
rf H: 90@a wp@a1,b=irr wp@b1--------------------------------------g=fulldec wp@h1----i=acqdec
-
rf 13C: wp@a2,b 180@c 90@d 90@e 180@f 90@g 90@h acq@h1----i
+
rf 13C: wp@a2,b=posramp 180@c 90@d 90@e 180@f 90@g 90@h acq@h1----i
rf 15N: wp@h1----i
rf 15N: wp@h1----i
Line 40: Line 40:
pulse p1: phase=phi1
pulse p1: phase=phi1
wp irr: h1=65
wp irr: h1=65
 +
wp posramp: h1=65 h2=95
 +
wp fulldec: h1=100 label=SPINAL
 +
wp acqdec: h1=75 label=SPINAL
acq: phase=phi2 type=fid
acq: phase=phi2 type=fid
Line 52: Line 55:
time: rlx @a t1 @b t2 @c t3 @d t4 @e t5 @f t4 @g t4 @h t6 @i d @j
time: rlx @a t1 @b t2 @c t3 @d t4 @e t5 @f t4 @g t4 @h t6 @i d @j
-
rf H: 90@a wp@a1,b wp@b1--h wp@i1--j
+
rf H: 90@a wp@a1,b wp@b1--h=fulldec wp@i1--j=acqdec
-
rf 13Cali: wp@a2,b shp@c 90@e 90@f shp@g 90@h 90@i acq@i2---------j
+
rf 13Cali: wp@a2,b=posramp shp@c 90@e 90@f shp@g 90@h 90@i acq@i2---------j
-
rf 13CO: wp@a2,b shp@d 90@e 90@f 90@h 90@i
+
rf 13CO: wp@a2,b=posramp shp@d 90@e 90@f 90@h 90@i
rf 15N: wp@i3,j
rf 15N: wp@i3,j
-
delay t1: show_at=13Cali label=ct label_yoffset=5
+
delay t1: show_at=13Cali label=ct label_yoffset=-30
delay t2: show_at=13Cali label=\tau-\frac{t_1}{2}
delay t2: show_at=13Cali label=\tau-\frac{t_1}{2}
delay t3: show_at=13Cali label=\tau+\frac{t_1}{2}
delay t3: show_at=13Cali label=\tau+\frac{t_1}{2}
Line 74: Line 77:
pulse p1: phase=phi1
pulse p1: phase=phi1
acq: phase=phi2 type=fid
acq: phase=phi2 type=fid
 +
 +
wp posramp: h1=65 h2=95
 +
wp fulldec: h1=100 label=SPINAL
 +
wp acqdec: h1=75 label=SPINAL
phase phi1: table=0,2 label=\phi_1
phase phi1: table=0,2 label=\phi_1

Revision as of 13:58, 4 September 2008

This page is a part of the user-editable NMR Wiki pulse sequence database.

Disclaimer: You are solely responsible for correct use of these materials on your instrument.

Ps.DB

search database
help.edit.pulsesequence.record

see edit instructions
help.adding.pulse.sequence

see deposition instructions
report.suggestions

report suggestions
Name: hCC-2D-CTUC COSY
Experiment family/families: solids
Synopsis: Constant-time Through-bond Carbon 2D correlation experiments
Implementation author(s): L. Chen, D.W. Elliot, J.M. Boetcher, D.H. Zhou, C.M. Rienstra, L.J. Mueller
Copyright: not assigned
Console: Varian, Infinity Plus, 500 MHz
Download: code, no sample/parameter data yet

CO-CA Version

Pulse sequence image

Aliphatic Version

Pulse sequence image

References

  1. Lee, YK and Kurur, ND and Helmle, M and Johannessen, OG and Nielsen, NC and Levitt, MH. Efficient dipolar recoupling in the NMR of rotating solids. A sevenfold symmetric radiofrequency pulse sequence. Chemical Physics Letters 242(3):304--309, 1995. BibTeX [levitt95]
  2. Hohwy, M and Jakobsen, HJ and Ed{\'e}n, M and Levitt, MH and Nielsen, NC. Broadband dipolar recoupling in the nuclear magnetic resonance of rotating solids: A compensated C7 pulse sequence. The Journal of Chemical Physics 108:2686, 1998. BibTeX [postc7]

  3. Rienstra, CM and Hatcher, ME and Mueller, LJ and Sun, B and Fesik, SW and Griffin, RG. Efficient Multispin Homonuclear Double-Quantum Recoupling for Magic-Angle Spinning NMR:\^{} 1\^{} 3C-\^{} 1\^{} 3C Correlation Spectroscopy of U-\^{} 1\^{} 3C-Erythromycin A. Journal of the American Chemical Society 120:10602--10612, 1998. BibTeX [cmr7]

  4. Hohwy, M and Rienstra, CM and Jaroniec, CP and Griffin, RG. Fivefold symmetric homonuclear dipolar recoupling in rotating solids: Application to double quantum spectroscopy. The Journal of Chemical Physics 110:7983, 1999. BibTeX [spc5]

Personal tools