2D CC-CTUC Solids
From NMR Wiki
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{{pulse-sequence | {{pulse-sequence | ||
- | |name=hCC-2D- | + | |name=hCC-2D-CTUC COSY |
- | |synopsis= | + | |synopsis=Constant-time Through-bond Carbon 2D correlation experiments |
|author=L. Chen, D.W. Elliot, J.M. Boetcher, D.H. Zhou, C.M. Rienstra, L.J. Mueller | |author=L. Chen, D.W. Elliot, J.M. Boetcher, D.H. Zhou, C.M. Rienstra, L.J. Mueller | ||
|code=I+CTUC_COSY.txt | |code=I+CTUC_COSY.txt | ||
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time: rlx @a t1 @b t2 @c t3 @d t4 @e t5 @f t5 @g t6 @h d @i | time: rlx @a t1 @b t2 @c t3 @d t4 @e t5 @f t5 @g t6 @h d @i | ||
- | rf H: 90@a wp@a1,b=irr wp@b1--------------------------------------g wp@h1----i | + | rf H: 90@a wp@a1,b=irr wp@b1--------------------------------------g=fulldec wp@h1----i=acqdec |
- | rf 13C: wp@a2,b 180@c 90@d 90@e 180@f 90@g 90@h acq@h1----i | + | rf 13C: wp@a2,b=posramp 180@c 90@d 90@e 180@f 90@g 90@h acq@h1----i |
rf 15N: wp@h1----i | rf 15N: wp@h1----i | ||
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pulse p1: phase=phi1 | pulse p1: phase=phi1 | ||
wp irr: h1=65 | wp irr: h1=65 | ||
+ | wp posramp: h1=65 h2=95 | ||
+ | wp fulldec: h1=100 label=SPINAL | ||
+ | wp acqdec: h1=75 label=SPINAL | ||
acq: phase=phi2 type=fid | acq: phase=phi2 type=fid | ||
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time: rlx @a t1 @b t2 @c t3 @d t4 @e t5 @f t4 @g t4 @h t6 @i d @j | time: rlx @a t1 @b t2 @c t3 @d t4 @e t5 @f t4 @g t4 @h t6 @i d @j | ||
- | rf H: 90@a wp@a1,b wp@b1--h wp@i1--j | + | rf H: 90@a wp@a1,b wp@b1--h=fulldec wp@i1--j=acqdec |
- | rf 13Cali: wp@a2,b shp@c 90@e 90@f shp@g 90@h 90@i acq@i2---------j | + | rf 13Cali: wp@a2,b=posramp shp@c 90@e 90@f shp@g 90@h 90@i acq@i2---------j |
- | rf 13CO: wp@a2,b shp@d 90@e 90@f 90@h 90@i | + | rf 13CO: wp@a2,b=posramp shp@d 90@e 90@f 90@h 90@i |
rf 15N: wp@i3,j | rf 15N: wp@i3,j | ||
- | delay t1: show_at=13Cali label=ct label_yoffset= | + | delay t1: show_at=13Cali label=ct label_yoffset=-30 |
delay t2: show_at=13Cali label=\tau-\frac{t_1}{2} | delay t2: show_at=13Cali label=\tau-\frac{t_1}{2} | ||
delay t3: show_at=13Cali label=\tau+\frac{t_1}{2} | delay t3: show_at=13Cali label=\tau+\frac{t_1}{2} | ||
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pulse p1: phase=phi1 | pulse p1: phase=phi1 | ||
acq: phase=phi2 type=fid | acq: phase=phi2 type=fid | ||
+ | |||
+ | wp posramp: h1=65 h2=95 | ||
+ | wp fulldec: h1=100 label=SPINAL | ||
+ | wp acqdec: h1=75 label=SPINAL | ||
phase phi1: table=0,2 label=\phi_1 | phase phi1: table=0,2 label=\phi_1 |
Revision as of 13:58, 4 September 2008
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Experiment family/families: solids
Synopsis: Constant-time Through-bond Carbon 2D correlation experiments
Implementation author(s): L. Chen, D.W. Elliot, J.M. Boetcher, D.H. Zhou, C.M. Rienstra, L.J. Mueller
Copyright: not assigned
Console: Varian, Infinity Plus, 500 MHz
Download: code, no sample/parameter data yet
CO-CA Version
Aliphatic Version
References
- Lee, YK and Kurur, ND and Helmle, M and Johannessen, OG and Nielsen, NC and Levitt, MH. Efficient dipolar recoupling in the NMR of rotating solids. A sevenfold symmetric radiofrequency pulse sequence. Chemical Physics Letters 242(3):304--309, 1995. BibTeX
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Hohwy, M and Jakobsen, HJ and Ed{\'e}n, M and Levitt, MH and Nielsen, NC. Broadband dipolar recoupling in the nuclear magnetic resonance of rotating solids: A compensated C7 pulse sequence. The Journal of Chemical Physics 108:2686, 1998. BibTeX
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Rienstra, CM and Hatcher, ME and Mueller, LJ and Sun, B and Fesik, SW and Griffin, RG. Efficient Multispin Homonuclear Double-Quantum Recoupling for Magic-Angle Spinning NMR:\^{} 1\^{} 3C-\^{} 1\^{} 3C Correlation Spectroscopy of U-\^{} 1\^{} 3C-Erythromycin A. Journal of the American Chemical Society 120:10602--10612, 1998. BibTeX
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Hohwy, M and Rienstra, CM and Jaroniec, CP and Griffin, RG. Fivefold symmetric homonuclear dipolar recoupling in rotating solids: Application to double quantum spectroscopy. The Journal of Chemical Physics 110:7983, 1999. BibTeX
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