2D CC-CTUC Solids
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(Difference between revisions)
Line 20: | Line 20: | ||
time: rlx @a t1 @b t2 @c t3 @d t4 @e t5 @f t5 @g t6 @h d @i | time: rlx @a t1 @b t2 @c t3 @d t4 @e t5 @f t5 @g t6 @h d @i | ||
- | rf H: 90@a | + | rf H: 90@a=phy wp@a1,b=posramp wp@b1--------------------------------------g=fulldec wp@h1----i=acqdec |
- | rf 13C: | + | rf 13C: wp@a2,b=irr 180@c=phx 90@d=phy 90@e=phx 180@f=phy 90@g=phx 90@h=phmx acq@h1----i |
rf 15N: wp@h1----i | rf 15N: wp@h1----i | ||
Line 30: | Line 30: | ||
delay t5: show_at=13C label=\tau | delay t5: show_at=13C label=\tau | ||
delay t6: show_at=13C label=\tau_{zf} | delay t6: show_at=13C label=\tau_{zf} | ||
+ | |||
+ | pulse p1: phase=phi1 | ||
+ | |||
+ | pulse phx: phase=px | ||
+ | pulse phmx: phase=mx | ||
+ | pulse phy: phase=py | ||
+ | |||
+ | phase px: label=x | ||
+ | phase py: label=y | ||
+ | phase mx: label=-x | ||
delay rlx: hide=true | delay rlx: hide=true | ||
Line 39: | Line 49: | ||
pulse p1: phase=phi1 | pulse p1: phase=phi1 | ||
- | wp irr: h1=65 | + | wp irr: h1=65 label=x |
- | wp posramp: h1=65 h2=95 | + | wp posramp: h1=65 h2=95 label=x |
wp fulldec: h1=100 label=SPINAL | wp fulldec: h1=100 label=SPINAL | ||
wp acqdec: h1=75 label=SPINAL | wp acqdec: h1=75 label=SPINAL | ||
Line 85: | Line 95: | ||
phase phi2: label=\phi_2 table=1,3 | phase phi2: label=\phi_2 table=1,3 | ||
</pulse> | </pulse> | ||
+ | |||
+ | ===CACO IPAP (IP) Version=== | ||
+ | <pulse> | ||
+ | anchors: @a,a1,a2 @b,b1 @c @c1,d,d1 @e @f @g @h------h1 @i | ||
+ | disp: 4@a 5@b 7@c 7@d 1@e 7@f 7@g 4@h 10@i | ||
+ | time: rlx @a t1 @b t2 @c t3 @d t4 @e t5 @f t5 @g t6 @h d @i | ||
+ | |||
+ | rf H: 90@a wp@a1,b=irr wp@b1--------------------------------------g=fulldec wp@h1----i=acqdec | ||
+ | rf 13C: wp@a2,b=posramp 180@c 90@d 90@e 180@f 90@g 90@h acq@h1----i | ||
+ | rf 15N: wp@h1----i | ||
+ | |||
+ | delay t1: show_at=13C label=ct label_yoffset=-30 | ||
+ | delay t2: show_at=13C label=\tau_1-\frac{t_1}{2} | ||
+ | delay t3: show_at=13C label=\tau_1+\frac{t_1}{2} | ||
+ | delay t4: hide=true | ||
+ | delay t5: show_at=13C label=\tau_2 | ||
+ | delay t6: show_at=13C label=\tau_{zf} | ||
+ | |||
+ | delay rlx: hide=true | ||
+ | delay d: hide=true | ||
+ | |||
+ | rfchan 13C: label=^{13}C | ||
+ | rfchan 15N: label=^{15}N | ||
+ | rfchan H: label=^1H | ||
+ | |||
+ | pulse p1: phase=phi1 | ||
+ | wp irr: h1=65 | ||
+ | wp posramp: h1=65 h2=95 | ||
+ | wp fulldec: h1=100 label=SPINAL | ||
+ | wp acqdec: h1=75 label=SPINAL | ||
+ | acq: phase=phi2 type=fid | ||
+ | |||
+ | phase phi1: table=0,2 label=\phi_1 | ||
+ | phase phi2: label=\phi_2 table=1,3 | ||
+ | </pulse> | ||
+ | |||
+ | ===CACO IPAP (AP) Version=== | ||
+ | <pulse> | ||
+ | anchors: @a,a1,a2 @b,b1 @c @c1,d,d1 @e @f @g @h------h1 @i | ||
+ | disp: 4@a 5@b 7@c 7@d 1@e 7@f 7@g 4@h 10@i | ||
+ | time: rlx @a t1 @b t2 @c t3 @d t4 @e t5 @f t5 @g t6 @h d @i | ||
+ | |||
+ | rf H: 90@a wp@a1,b=irr wp@b1--------------------------------------g=fulldec wp@h1----i=acqdec | ||
+ | rf 13C: wp@a2,b=posramp 180@c 90@d 90@e shp@f=COsoft acq@h1----i | ||
+ | rf 15N: wp@h1----i | ||
+ | |||
+ | delay t1: show_at=13C label=ct label_yoffset=-30 | ||
+ | delay t2: show_at=13C label=\tau_1-\frac{t_1}{2} | ||
+ | delay t3: show_at=13C label=\tau_1+\frac{t_1}{2} | ||
+ | delay t4: hide=true | ||
+ | delay t5: show_at=13C label=\tau_2 | ||
+ | delay t6: show_at=13C label=\tau_{zf} | ||
+ | |||
+ | delay rlx: hide=true | ||
+ | delay d: hide=true | ||
+ | |||
+ | rfchan 13C: label=^{13}C | ||
+ | rfchan 15N: label=^{15}N | ||
+ | rfchan H: label=^1H | ||
+ | |||
+ | pulse p1: phase=phi1 | ||
+ | wp irr: h1=65 | ||
+ | wp posramp: h1=65 h2=95 | ||
+ | wp fulldec: h1=100 label=SPINAL | ||
+ | wp acqdec: h1=75 label=SPINAL | ||
+ | acq: phase=phi2 type=fid | ||
+ | |||
+ | phase phi1: table=0,2 label=\phi_1 | ||
+ | phase phi2: label=\phi_2 table=1,3 | ||
+ | </pulse> | ||
+ | |||
==References== | ==References== |
Revision as of 21:45, 4 September 2008
This page is a part of the user-editable NMR Wiki pulse sequence database.
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Experiment family/families: solids
Synopsis: Constant-time Through-bond Carbon 2D correlation experiments
Implementation author(s): L. Chen, D.W. Elliot, J.M. Boetcher, D.H. Zhou, C.M. Rienstra, L.J. Mueller
Copyright: not assigned
Console: Varian, Infinity Plus, 500 MHz
Download: code, no sample/parameter data yet
CO-CA Version
Aliphatic Version
CACO IPAP (IP) Version
CACO IPAP (AP) Version
References
- Chen, L and Olson, RA and Elliot, DW and Boettcher, JM and Zhou, DH and Rienstra, CM and Mueller, LJ. Constant-Time Through-Bond ^{13}C Correlation Spectroscopy for Assigning Protein Resonances with Solid-State NMR Spectroscopy. J Am Chem Soc 128(31):9992--9993, 2006. BibTeX
-
Chen, L and Kaiser, JM and Lai, J and Polenova, T and Yang, J and Rienstra, CM and Mueller, LJ. J-based 2D homonuclear and heteronuclear correlation in solid-state proteins. Magn Reson Chem 45 suppl.:s84-s92, 2007. BibTeX
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