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This are example nitroxide spin labels used for biomolecular NMR.  Image is taken from Clore_Iwahara_2009, chemical reviews. (Clore, G. M., and Iwahara, J. (2009) Theory, practice, and applications of paramagnetic relaxation enhancement for the characterization of transient low-population states of biological macromolecules and their complexes, Chem Rev 109, 4108-4139)

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