Determination of relative stereochemistry

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This review article discusses use of ^2,3J_CH, ³J_HH scalar couplings and ¹³C chemical shifts for assignment of relative stereochemistry in flexible acyclic substituted hydrocarbons.

[1] Giuseppe Bifulco, Paolo Dambruoso, Luigi Gomez-Paloma, and Raffaele Riccio, "Determination of Relative Configuration in Organic Compounds by NMR Spectroscopy and Computational Methods", Chem. Rev.; 2007; 107(9) pp 3744 - 3779