Residual dipolar coupling
From NMR Wiki
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pages={193-232}, | pages={193-232}, | ||
year={2009}, | year={2009}, | ||
| + | chapter={4}, | ||
url={http://dx.doi.org/10.1016/S0066-4103(09)06804-5}, | url={http://dx.doi.org/10.1016/S0066-4103(09)06804-5}, | ||
abstract={Residual dipolar couplings (RDCs) have already revolutionized biomolecular NMR spectroscopy and are about to do the same in small molecule applications: impressive examples for conformational refinement of small sugars and peptides, the distinction of enantiomers and the determination of relative and absolute configuration have been published in recent years. After a short introduction into the basic theory, this article will give a review of existing alignment media, methods for scaling the alignment, pulse sequences for measuring RDCS and recent applications.} | abstract={Residual dipolar couplings (RDCs) have already revolutionized biomolecular NMR spectroscopy and are about to do the same in small molecule applications: impressive examples for conformational refinement of small sugars and peptides, the distinction of enantiomers and the determination of relative and absolute configuration have been published in recent years. After a short introduction into the basic theory, this article will give a review of existing alignment media, methods for scaling the alignment, pulse sequences for measuring RDCS and recent applications.} | ||
