2D CC-CTUC Solids

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	|name=hCC-2D-CTUC COSY		|name=hCC-2D-CTUC COSY
	|synopsis=Constant-time Through-bond Carbon 2D correlation experiments		|synopsis=Constant-time Through-bond Carbon 2D correlation experiments
-	|author=L. Chen, D.W. Elliot, J.M. Boetcher, D.H. Zhou, C.M. Rienstra, L.J. Mueller	+	|author=Lindsay Sperling, Gemma Commellas, Trent Franks, Chad Rienstra
	|code=I+CTUC_COSY.txt		|code=I+CTUC_COSY.txt
	|source=UIUC		|source=UIUC

---

Revision as of 16:08, 5 September 2008

Name: hCC-2D-CTUC COSY
Experiment family/families: solids
Synopsis: Constant-time Through-bond Carbon 2D correlation experiments
Implementation author(s): Lindsay Sperling, Gemma Commellas, Trent Franks, Chad Rienstra
Copyright: not assigned
Console: Varian, Infinity Plus, 500 MHz
Download: code, no sample/parameter data yet

Implementation

All needed files were catenated together, and so must be separated. The file CTUC_COSY.acq is the first block of text after the author contributions. CTUC_COSY.s begins with

    name	"2D_CC_shell";

and ends with

    return;

The next several files should be separated and placed in /export/homes/USERNAME/pulse_sequences/cpc/includes. Each new file begins with a long comment section. The files acq.inc, CTUC_COSY.acq, CTUC_COSY.s, rSNOB_063108.inc, rSNOB_delay2.incSPC5.inc, SPINAL1.inc, SPINAL2.inc, STANDARD_PARAMS, std_errs.inc, t1.inc, t2.inc, TAN_CP.inc, and TWO_D.inc should be created from this file.

CO-CA Version

The hard pulse version of the experiment can be used if soft_pulse_flag=0 and ipap_flag=0.

Aliphatic Version

The soft pulse version of the experiment can be used if soft_pulse_flag=1 and ipap_flag=0.

CACO IPAP (IP) Version

The IP version of the experiment can be used if soft_pulse_flag=0 and ipap_flag=0, with the carrier placed on resonance with the Carbonyl frequency.

CACO IPAP (AP) Version

The AP version of the experiment can be used if ipap_flag=1 (independent of soft_pulse_flag), with the carrier placed on resonance with the Carbonyl frequency.

References

1. Chen, L and Olson, RA and Elliot, DW and Boettcher, JM and Zhou, DH and Rienstra, CM and Mueller, LJ. Constant-Time Through-Bond ^{13}C Correlation Spectroscopy for Assigning Protein Resonances with Solid-State NMR Spectroscopy. J Am Chem Soc 128(31):9992--9993, 2006. BibTeX [bbCTUC]

2. Chen, L and Kaiser, JM and Lai, J and Polenova, T and Yang, J and Rienstra, CM and Mueller, LJ. J-based 2D homonuclear and heteronuclear correlation in solid-state proteins. Magn Reson Chem 45 suppl.:s84-s92, 2007. BibTeX [ipapCTUC]